Foaming

Air (dissolved or dispersed) is a general problem with oils.

This problem is combated with various additives. Some additives inhibit the foaming characteristics (less foam or instable bubble formation) and others improve the outflow of air (improved air separation characteristics). Silicon oil, for instance, inhibits the foaming properties, but reduces the air separation characteristics.

Dissolved Air in Lubricants (Bartz, Page 115)
Liquid Air percentage in 1013 mbar and 20°C [%]
Mineral oil 7–9
Silicon oil 15–25
Dicarbon acid ester approx. 9
Phosphate ester approx. 9
PCB approx. 4
Water 1.87

Tests at Intertek with Defoamers and Breathers

We examined the effect of various defoamers and breathers (separately and in combination) in a laboratory experiment.

Tests with Defoamers and Breathers

Sample: Shell Tellus 46, approx. 12 years in use (turbines/gears with transmission failure)

Analysis 180437

Shell Tellus 46

Experiment 1 Experiment 2 Experiment 3 Experiment 4 Experiment 5
Appearance brown-yellow, clear
Breather EEK (0.05%) EEK (0.05%)
Defoamer MKO 812 (20ppm) MYW (0.025%) CHB (0.2%) MYW (0.025%)
Odour rancid
Viscosity at 40°C 44.8
Neutralisation number 0.5
Fl >= 100
Fll >= 100
Water content (coulometry.) 40
Air separation characteristic 7.2 4.3 7.5 7.6
Sequence I (24°C) 500 270 10 10 10 0
Sequence ll (93.5°C) 50 30 20 10 20 10
Sequence III (24°C according to Seq. II) 500 200 10 30 0 0

Dissolved Air in Lubricants (Bartz, Page 115)

Liquid Air percentage in 1013 mbar and 20°C [%]
Mineral oil 7–9
Silicon oil 15–25
Dicarbon acid ester approx. 9
Phosphate ester approx. 9
PCB approx. 4
Water 1.87